16 March 2009

On the language of chemistry: the obvious and the unsaid

(A written shortened version of the talk given at the English Department, University of Pune)

Chemistry(etymology: Chymistry, with the purpose of studying the properties of dyes) was said to be thought of as an experimental science which had developed through touch, feel, taste perceptions. Its initial developments and systematics came from solutions, substances that could be weighed in specific metric systems and colours that could be recognized by human perceptions. These led to some empirical rules and classification. Formulating the combination of substances required the basic assumption of the existence of atoms without seeing them. This was probably the first instance of the use of an entity that could not be seen or felt but was just percieved. The first step in this was the formuation of a periodic table, assuming the existence of atoms as basic entities. This was at a time when atoms could not even be seen or understood.

A very interesting connection with this is often seen in literature, media and cartoons, when the chemist is shown as one who broods over over smoking vessels of exotic morphology filled with liquids of colours that capture your imagination. An example that is close to your hearts would be the honorary membership of Sherlock Holmes to the Royal Society of Chemists in 2002. The declaration was made by the secretary at that time James Watson and it states due to his valuable contributions to detective science via his abilities in chemistry.

Taking a jump from here to the 1930's (after the electron was discovered in 1897, and the atom was instrumentally found to exist with its basic structure known), the beginnings of quantum mechanics started changing the subject. The first thing that we learn in school after the periodic table is something called an electronic configuration which is based on certain terms such as orbitals which are derived from quantum mechanics. This courses on to several other noumenal terms like bonding, valence, reactivity so on and so forth.

Thus did language of chemistry evolve and it went onto get a symbolic language of its own, derived from Latin, Greek and some sort of chemical heiroglyphics. This chemical heiroglyphics involved alphabets, single straight lines for bonds, forward and backward arrows for reactions, upward arrows for gases evolving in reactions, downward arrows for substances settling down in solutions, and even curly arrows for the movement of electrons in organic reactions. The development of the subject required notations. It all went on to such an extent that a chemists basic reasoning and communication was along the lines of this heiroglyphics. Rules were put down for it.

With years gone by to the present, the boundaries of chemistry have slowly started dissolving. The development of quantum mechanics has brought about the development of quantum chemistry. More sophisticated instruments have brought about the a feeling that the previous perception of atoms was not just a noumenon. The chemists have now actually started seeing molecules instead of just drawing logical conclusions as to what they look like. Computers and their advancement have facilitated the perception of molecules in terms of numbers that could be picturised. So now molecules look like this, in terms of abstract numbers which evolved into pictures. Hence the language of chemistry involving bonds and electrons moving on arrows in reactions have become a seeming reality.



But still the traditional chemist educated via all the chemical language that brought the subject to him, does have steadfast belief in all the empirical factors that he has studied. Due to this several so-called surprising interpretations pop up from time to time, exceptions that do not follow the empirical rules set up and the heiroglyphics. It is in order to understand these exceptions that one has to resort to forgetting what we have been traditionally taught. For example in our schools we say that carbon in methane will always have only 4 other neighbouring atoms arranged in four corners of a tetrahedron. But of recent several other variants of the same compound have been found.

In order to easily facilitate, such new developments it is perhaps necessary to understand that bonds, valence, electronegativity, and all the other terms which we learn in school do not really exist. They are a noumenon in the sense of Kant and serve as only as means of communication.
But at this point there is always that relevant question how else do we depict chemistry, when it is a medium to be taught, understood and communicated.
A change in the language is not really required. The best one can do is instill doubts in the minds of people regarding the absoluteness of the concepts that we learn. The doubt remains with the person and that bit of it helps him in advancing the science beyond traditional beliefs and perception. (Afterall it is just a historical accident that the electrons are negatively charged and the atoms are positive) In this sense, science is not very different from literature and language. Although science proceeds from observations and experiment it is finally the interpretation that advances it. The same is probably the case for languages.

15 March 2009

About my Ph.D.

I am 31 years old, and that is slightly less than half of the Biblical life expectancy of 70 (Psalm 90:10) . Not that I believe in anything, I am completely indifferent to what they call spirituality. Even if it is something to do with a peace of mind or that strange something happiness that people have told me they feel when they do whatever it is to gain such a state of mind; I still will not believe in it. I just do not want that kind of a self satisfaction. There are always other ways. And one of those turned out to be a Ph. D...

"The origins of the doctorate dates back to the ijazat attadris wa 'l-iftta ("license to teach and issue legal opinions") in the medieval Madrasahs from the 9th century, though it was limited to Islamic law at the time, as in a Doctor of Laws degree."...Thats from Wikipedia...

As it turns out blogging and Wikipedia were not yet a practice when I started doing my Ph. D in 2000. I was just another bloke fresh from my post graduate degree in Chemistry, quite self assured and confident that there is nothing else that I wanted to do in life at that moment. Even then, it was not about the degree. I wanted to work in Quantum Chemistry, so in August 2000, I joined a lab.

I will leave out a lot of information here, helps preserve a little indifference.

What I have just told told you is how simple, uneventful and beautiful the beginning was. Now, you could just fast forward yourself to July 2008, and leave all the rest out of the equation. On the 22nd of July 2008, my 31st birthday, I submitted my thesis. Another quick fast forward to December 30th 2008, and they told me that I had successfully defended my thesis. That was the end of my Ph. D. days, as simple and uncomplicated as it seemed. And then on January 15th 2009, there was this blog (the current dates have been modified and republished) http://anujis.blogspot.com/2009/03/phd-phd.html

To tell you the truth, this post (in its current form) is pretty professional and the author definitely has a very clear analytical mind. It was not so in its original form. In a nutshell, it discusses the years, the publications, the quality of being organized and in the end there is a question and a judgement. The judgement says:

"According to me the number of years does not matter, but no country should allow PhD to stretch out for 10 years. I am sure if he or she would have been better organized could have finished the same amount of work in 5 years or even less. I assume that people taking 10 years to finish their PhD is just stretching out their work by sleeping off half the time or are there some other factors behind a long PhD? I think it is high time that India or any other country has to change this scenario completely."

When the number of years does not matter, what's 10 years to finish , 5 years or even less and long PhD?

And then there is a moral for everyone who wants to do a Ph. D.

"For those who would like to do a PhD, never take it for granted and finish it fast and efficiently."

Hallelujah!...For those who want a PhD, you should definitely do what it says, at the end of all that you will have a degree and you can be happy and make others happy. As for the "India or any other country" blah blah blah part, its your country, you have to be in India to know it. And you definitely do make a difference by blogging on the conditions of your own country. For that matter I believe that there should not be a time limit on a PhD.

As for those assumed people taking 10 years to finish their PhD is just stretching out their work by sleeping off half the time, whoops! That is where I come in, after doing a PhD for 8.5 years. Probably, this blog thinks that it knows me better than me, myself and my nonchalance. This thought of the blog is not all that surprising, with all due respect to my past historical connections with the author of the blogged post. People will always think that they know you better than yourself. There is always a lot that is left unsaid, and I plan to leave it like that.

The fast world and its competitions are yet another matter. We know the tale of the tortoise and the hare. What they never tell us at the end of the tale is that, eventhough the tortoise wins, the hare is always faster.

To end this note, I have to tell you people a secret.

I never cared too much about the titled degree, I have enjoyed working for 8.5 years on this subject, in this place, with my supervisor, with friends, at my small desk and computer. During this time I have done 50% of everything that I wanted. What more could I ask for?...Not the other 50% ...

I think that is what a Ph. D is all about...

...And on a personal not so indifferent note ... I will miss all this when I go...